Evaluation of Micronized Ilmenite as Weighting Material in Water-Based Drilling Fluids for HPHT Applications

Paper presented at SPE Kuwait International Petroleum Conference and Exhibition, Kuwait City, Kuwait, December 2012.


Barite is the most common weighting material for drilling fluids, which contain several heavy components including lead, cadmium, mercury, and arsenic. Some of these heavy materials can discharge into the sea, which is not allowed especially in the case of oil-based drilling fluid. The supply of barite is geographically limited, with high transportation costs. To overcome the high cost, shortage, and common problems of barite, an alternative weighting material, ilmenite (5 µm), is introduced which is heavier than barite and more stable at high temperature. Also, the micronized ilmenite was introduced to overcome the ECD challenges in some drilling operations at reasonable cost. Extensive lab work was done in order to: 1) optimize the rheological properties of the drilling fluid, 2) determine the optimum pH that gives stable dispersion, 3) assess the thermal stability, 4) optimize the filtration parameters (filtrate volume and filter cake thickness), and 5) characterize the ilmenite-based filter cake. Zeta potential results showed that ilmenite was stable when mixed with water at a pH above 7 and it was dispersed and stable when mixed with the drilling fluid components. Drilling fluids have a density range from 100 to 120 pcf and a plastic viscosity of 28–32 cp. No phase separation was observed after hot rolling for 16 hrs at 300°F. The optimized water-based drilling fluid formula had a small filtrate volume (12 cm3) and thin filter cake (0.2 in.) under dynamic conditions. SEM analysis showed that ilmenite filter cake was heterogeneous and contained ilmenite particles in the layer closer to the rock surface. The layer closer to the drilling surface had a mixture of xanthan gum and modified starch, which were used to optimize the rheological properties at 250°F. This study will provide a complete evaluation of the drilling fluids with ilmenite as a weighting material and will help drilling engineers to better design drilling fluids for HPHT wells.